Organic chemistry We provide online tutoring & assignment assistance in High School Chemistry We have a team of highly qualified tutors who have minimum of 2000 hours of online tutoring experience We would love to work with you in both instant scheduled & assignment help Alkenes Free-Radical Substitution Stereochemistry I Stereoisomers Classification by structure the family Structure of ethane Free rotation about the carbon-carbon single bond Conformations Torsional strain Propane and the butanes Conformations of n-butane Van der Waals repulsion Higher alkanes The homologous series Nomenclature Alkyl groups Common names of alkanes IUPAC names of alkanes Classes of carbon atoms and hydrogen atoms Physical properties Industrial source Industrial source vs laboratory preparation The Grignard reagent an organometallic compound Coupling of alkyl halides with organometallic compounds Halogenation Mechanism of halogenations Orientation of halogenations Relative reactivities of alkanes towards halogenations Ease of abstraction of hydrogen atoms Energy of activation Stability of free radicals Ease of formation of free radicals Transition state for halogenations Orientation and reactivity Reactivity and selectivity Non-rearrangement of free radicals Isotopic tracers Combustion The greenhouse effect Pyrolysis cracking Determination of structure Analysis of alkanes Stereochemistry and stereoisomerism Isomer number and tetrahedral carbon Optical activity Plane-polarized light The polarimeter Specific rotation Enantiomerism and tetrahedral carbon Enantiomerism and optical activity Prediction of enantiomerism Chirality The chiral center Enantiomers he racemic modification Optical activity a closer look Configuration Specification of configuration R and S Sequence rules Diastereomers Meso structures Specification of configuration more than one chiral center Conformational isomers Reactions involving stereoisomers Generation of a chiral center Synthesis and optical activity Reactions of chiral molecules Bond-breaking Reactions of chiral molecules Relating configurations Optical purity Reactions of chiral molecules Generation of a second chiral center Reactions of chiral molecules with optically active reagents Resolution Reactions of chiral molecules Mechanism of free-radical chlorination
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