Organic chemistry We provide online tutoring & assignment assistance in High School Chemistry We have a team of highly qualified tutors who have minimum of 2000 hours of online tutoring experience We would love to work with you in both instant scheduled & assignment help Conjugation and Resonance Dienes Alkynes The carbon-carbon double bond as a substituent Free-radical halogenation of alkenes substitution vs addition Free-radical substitution in alkenes orientation and reactivity Free-radical substitution in alkenes allylic rearrangement Symmetry of the allyl radical The theory of resonance The allyl radical as a resonance hybrid Stability of the allyl radical Orbital picture of the allyl radical Resonance stabilization of alkyl radicals Hyperconjugation The allyl cation as a resonance hybrid Nucleophilic substitution in allylic substrates SN1 Reactivity Allylic rearrangement Stabilization of carbocations the resonance effect Nucleophilic substitution in allylic substrates SN2 Nucleophilic substitution in vinylic substrates Vinylic cations Dienes structure and properties Stability of conjugated dienes Resonance in conjugated dienes Resonance in alkenes Hyperconjugation Ease of formation of conjugated dienes orientation of elimination Electrophilic addition to conjugated dienes 14-Addition 12- vs 14-Addition Rate vs equilibrium Free-radical polymerization of dienes Rubber and rubber substitutes Isoprene and the isoprene rule Analysis of dienes Structure of acetylene The carbon-carbon triple bond Higher alkynes Nomenclature Physical properties of alkynes Preparation of alkynes Reactions of alkynes Reduction of alkenes Electrophilic addition to alkynes Hydration ofalkynes Tautomerism Acidity ofalkynes Very weak acids Reactions of metal acetylides Synthesis of alkynes Formation of carbon-carbon bonds Role played by organometallic compounds Analysis of alkynes
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